必搏体育

必搏体育:有机化学硕士点简介

发布者:信息发布员发布时间:2021-04-12浏览次数:1274


一、硕士点概况


有机化学硕士点建立于2003年,设仿生不对称催化、多相不对称催化、绿色不对称合成、有机金属催化、有机功能材料等研究方向。先后承担国家自然科学基金项目、国家“十.五”科技攻关项目、上海市基础研究重大项目、上海市基础研究重点项目、上海市重点科技攻关项目、上海市教委项目等多项科研项目。


二、研究方向


  1. 仿生不对称催化;

  2. 多相不对称催化;

  3. 绿色不对称合成;

  4. 有机金属催化;

  5. 有机功能材料;


三、师资队伍


有机化学硕士点共有校内导师硕士生13人,其中教授5人:刘国华,赵宝国,邓清海,程探宇,肖晓;副教授8人:肖海波,谭春霞,陈键锋,陈雯雯,曹晶,金荣华,林静容,许东方。校外兼职硕士生导师十余人:曹春阳、邓亮、高希珂、洪缪、黄乃正、金健、李维实、林国强、刘文、王东辉、肖吉昌、赵新、赵延川、支志明,董佳家、杨军。


四、代表性论文


  1.  Jianfeng Chen, Xing Gong, Jianyu Li, Yingkun Li, Jiguo Ma, Chengkang Hou, Guoqing Zhao, Weicheng Yuan*, Baoguo Zhao*, Carbonyl catalysis enables a biomimetic asymmetric Mannich reaction, Science, 2018, 360, 1438.

  2.  Yong Ethan Liu, Zhaole Lu, Bo Li, Jiaxin Tian, Feng Liu, Junyu Zhao, Chengkang Hou, Yingkun Li, Lili Niu, and Baoguo Zhao*, Enzyme-Inspired Axially Chiral Pyridoxamines Armed with a Cooperative Lateral Amine Chain for Enantioselective Biomimetic Transamination, Journal of the American Chemical Society,2016, 138, 10730.

  3.  Fengwei Chang, Shitong Wang, Zhitong Zhao, Lijian Wang, Tanyu Cheng, and Guohua Liu*, Enantioselective Dual-Catalysis: A Sequential Michael Addition/Asymmetric Transfer Hydrogenation of α-Nitrosulfone and Enones, ACS Catalysis, 2020, 10, 10381.

  4.  Jingjing Meng, Fengwei Chang, Yanchao Su, Rui Liu, Tanyu Cheng, and Guohua Liu*, Switchable Catalysts Used To Control Suzuki Cross-Coupling and Aza?Michael Addition/Asymmetric Transfer Hydrogenation Cascade Reactions, ACS Catalysis, 2019, 9, 8693.

  5.  Yanchao Su, Fengwei Chang, Ronghua Jin, Rui Liu and Guohua Liu*, Hetero-bifunctional catalyst manipulates carbonyl and alkynyl reductions of conjugated alkynones in an aqueous medium, Green Chemistry, 2018, 20, 5397.

  6.  Xiaomin Shu, Ruihua Jin, Zhongrui Zhao, Tanyu Cheng and Guohua Liu*, An Integrated Immobilization Strategy Manipulates Dual Active Centers to Boost Enantioselective Tandem Reaction, Chemical Communications,2018, 54, 13244.

  7.  Chong-Ji Wang, Jian Sun, Wei Zhou, Jing Xue, Bing-Tao Ren, Guang-Yi Zhang, Yan-Le Mei, Qing-Hai Deng*, Enantioselective Copper-Catalyzed Electrophilic Dearomative Azidation of β-Naphthols, Organic Letters, 2019, 21, 7315.

  8.  Yi Peng, Yan-Hui Fan, Si-Yuan Li, Bin Li, Jing Xue, Qing-Hai Deng*, Iron-Catalyzed Nitrene Transfer Reaction of 4-Hydroxystilbenes with Aryl Azides: Synthesis of Imines via C═C Bond Cleavage, Organic Letters,2019, 21, 8389.

  9.  Rui Liu,* Yajie Chou, Bing Lian, De-cai Fang, Ming Gao, Tanyu Cheng, and Guohua Liu*, Mechanistic Insights into the Ru(II)-Catalyzed Intramolecular Formal [3 + 2] Cycloaddition of (E) 1,6-Enynes, Organic Letters, 2019, 21, 6815.

  10. Ming Gao, Qiangqiang Gao, Xiangbin Hao, Ying Wu, Qingmin Zhang, Guohua Liu, Rui Liu*, Ruthenium Carbene-Mediated Construction of Strained Allenes via the Enyne Cross-metathesis/Cyclopropanation of 1,6-Enynes,Organic Letters, 2020, 22, 1139.


五、主要科研项目


  1. 国家自然科学基金委面上项目:“手性吡哆醛仿生催化氨基酸衍生物的不对称aldol反应和Mannich反应的研究

  2. 国家自然科学基金委面上项目:“可切换型双功能催化剂用于远程链状的两个手性碳骨架中心的构建研究

  3. 国家自然科学基金委面上项目:“基于Retro-Michael/Michael加成和不对称氢转移反应的β-取代酮动态动力学拆分研究

  4. 国家自然科学基金委面上项目:“基于二吡咯亚甲基骨架的NNNN型手性光敏配体的合成及其在不对称光致氧气氧化反应中的应用研究

  5. 国家自然科学基金委面上项目:“催化活性点分离的双功能负载型催化剂的构建和串联不对称反应研究

  6. 国家自然科学基金委青年项目:“基于精准捕获钌卡宾中间体策略的炔烃偶联反应合成联烯的研究

  7. 国家自然科学基金委青年项目:“氧化-还原串联催化功能导向构筑双活性金属-有机分子笼


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